Composition dependence of giant electrocaloric effect in Pb_xSr_1-xTiO₃ ceramics for energy-related applications(PDF)

Journal of Materiomics[ISSN:/CN:]

volumne:

Issue:

2019Äê01ÆÚ

Page:

118-126

Research Field:

Publishing date:

2019-03-30

Info

Title:

Composition dependence of giant electrocaloric effect in Pb_xSr_1-xTiO₃ ceramics for energy-related applications

Highlights:

Peng-Zu Ge^a; Xiao-Dong Jian^b; Xiong-Wei Lin^b; Xin-Gui Tang^a; Zhi Zhu^a; Qiu-Xiang Liu^a; Yan-Ping Jiang^a; Tian-Fu Zhang^a; Sheng-Guo Lu^b

^aSchool of Physics and Optoelectric Engineering, Guangdong University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou, 510006, China;^bSchool of Materials and Energy, Guangdong University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou, 510006, China

Keywords:

Pb_xSr_1-xTiO₃ ceramics; Electrocaloric effect; Phase transition; Energy applications

PACS:

-

DOI:

https://doi.org/10.1016/j.jmat.2018.10.002

Abstract:

Pb_xSr_1-xTiO₃ (x?=?0.30, 0.35, 0.40, 0.45, 0.50 and 0.55) ceramics were fabricated by a solid-state reaction route. X-ray diffraction data at room temperature show PST samples shift from cubic to tetragonal phase with the increase of Pb²⁺ content. The microstructures were observed by scanning electron microscopy. Dielectric measurement was employed to investigate the ferroelectric-paraelectric phase transition behavior. Temperature dependent polarization-electric field hysteresis loops were conducted to study the electrocaloric effect (ECE) of the ferroelectric ceramics by indirect methods over a wide temperature range. Direct measurement of temperature change (¦¤T) at room temperature for all samples can achieve 0.79-1.86?K. What's more, a giant ECE (¦¤T?=?2.05?K, EC strength (¦¤T/¦¤E)?=?0.51?¡Á?10^?6?K?m/V, under 40?kV/cm) was obtained in the sample of x?=?0.35 near phase transition temperature. Our results suggest that the ceramics are promising cooling materials with excellent EC properties for energy related applications.

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